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GOLD [[[symbol]] Au, atomic weight 1 95.7(11 = I),197

2(O =16)], a metallic chemical element, valued from the earliest ages on account of the permanency of its colour and lustre. Gold ornaments of great variety and elaborate workmanship have been discovered on sites belonging to the earliest known civilizations, Minoan, Egyptian, Assyrian, Etruscan (see Jewelry, Plate, Egypt, Crete, Aegean Civilization, Numismatics), and in ancient literature gold is the universal symbol of the highest purity and value (cf. passages in the Old Testament, e.g. Ps. xix. 10 " More to be desired are they than gold, yea, than much fine gold "). With regard to the history of the metallurgy of gold, it may be mentioned that, according to Pliny, mercury was employed in his time both as a means of separating the precious metals and for the purposes of gilding. Vitruvius also gives a detailed account of the means of recovering gold, by amalgamation, from cloth into which it had been woven.

1 Physical Properties

2 Chemical Properties

3 Occlusion of Gas by Gold

4 Occurrence and Distribution

5 Statistics of Gold Production

6 Gold and Palladium

7 Gold and Nickel

8 Gold and Cobalt

9 Compounds

10 Separation of Gold from the Amalgam

11 Extraction by Means of Aqueous Solutions

12 Refining or Parting of Gold

13 AuTxoRITIEs

Physical Properties

Gold has a characteristic yellow colour, which is, however, notably affected by small quantities of other metals; thus the tint is sensibly lowered by small quantities of silver, and heightened by copper. When the gold is finely divided, as in " purple of Cassius," or when it is precipitated from solutions, the colour is ruby-red, while in very thin leaves it transmits a greenish light. It is nearly as soft as lead and softer than silver. When pure, it is the most malleable of all metals (see Goldbeating). It is also extremely ductile; a single grain may be drawn into a wire 500 ft. in length, and an ounce of gold covering a silver wire is capable of being extended more than 1300 m. The presence of minute quantities of cadmium, lead, bismuth, antimony, arsenic, tin, tellurium and zinc renders gold brittle, 2 ' 0 15th part of one of the three metals first named being sufficient to produce that quality. Gold can be readily welded cold; the finely divided metal, in the state in which it is precipitated from solution, may be compressed between dies into disks or medals. The specific gravity of gold obtained by precipitation from solution by ferrous sulphate is from 19.55 to 20.72. The specific gravity of cast gold varies from 18.29 to 19.37, and by compression between dies the specific gravity may be raised from 19.37 to 19.41; by annealing, however, the previous density is to some extent recovered, as it is then found to be 19.40. The melting-point has been variously given, the early values ranging from 1425° C. to 1035° C. Using improved methods, C. T. Heycock and F. H. Neville determined it to be 1061

7° C.; Daniel Berthelot gives 1064° C., while Jaquerod and Perrot give 1066.1-1067.4° C. At still higher temperatures it volatilizes, forming a reddish vapour. Macquer and Lavoisier showed that when gold is strongly heated, fumes arise which gild a piece of silver held in them. Its volatility has also been studied by L. Elsner, and, in the presence of other metals, by Napier and others. The volatility is barely appreciable at 1075°; at 1250° it is four times as much as at 1 roo°. Copper and zinc increase the volatility far more than lead, while the greatest volatility is induced, according to T. Kirke Rose, by tellurium. It has also been shown that gold volatilizes when a gold-amalgam is distilled. Gold is dissipated by sending a powerful charge of electricity through it when in the form of leaf or thin wire. The electric conductivity is given by A. Matthiessen as 73 at 0° C., pure silver being 100; the value of this coefficient depends greatly on the purity of the metal, the presence of a few thousandths of silver lowering it by 10%. Its conductivity for heat has been variously given as 103 (C. M. Despretz), 98 (F. Crace-Calvert and R. Johnson), and 60 (G. H. Wiedemann and R. Franz), pure silver being loo. Its specific heat is between 0.0298 (Dulong and Petit) and 0.03244 (Regnault). Its coefficient of expansion for each degree between o° and Ioo C. is 0.000014661, or for gold which has been annealed 0.000015136 (Laplace and Lavoisier). The spark spectrum of gold has been mapped by A. Kirchhoff, R. Thaler', Sir William Huggins and H. Kriiss; the brightest lines are 6277, 59 60, 5955 and 5836 in the orange and yellow, and 5230 and 4792 in the green and blue.

Chemical Properties

Gold is permanent in both dry and moist air at ordinary or high temperatures. It is insoluble in hydrochloric, nitric and sulphuric acids, but dissolves in aqua regia - a mixture of hydrochloric and nitric acids - and when very finely divided in a heated mixture of strong sulphuric acid and a little nitric acid; dilution with water, however, precipitates the metal as a violet or brown powder from this solution. The metal is soluble in solutions of chlorine, bromine, thiosulphates and cyanides; and also in solutions which generate chlorine, such as mixtures of hydrochloric acid with nitric acid, chromic acid, antimonious acid, peroxides and nitrates, and of nitric acid with a chloride. Gold is also attacked when strong sulphuric acid is submitted to electrolysis with a gold positive pole. W. Skey showed that in substances which contain small quantities of gold the precious metal may be removed by the solvent action of iodine or bromine in water. Filter paper soaked with the clear solution is burnt, and the presence of gold is indicated by the purple colour of the ash. In solution minute quantities of gold may be detected by the formation of " purple of Cassius," a bluish-purple precipitate thrown down by a mixture of ferric and stannous chlorides.

The atomic weight of gold was first determined with accuracy by Berzelius, who deduced the value 195.7 (H= i) from the amount of mercury necessary to precipitate it from the chloride, and 195.2 from the ratio between gold and potassium chloride in potassium aurichloride, KAuC1 4. Later determinations were made by Sir T. E. Thorpe and A. P. Laurie, Kriiss and J. W. Mallet. Thorpe and Laurie converted potassium auribromide into a mixture of metallic gold and potassium bromide by careful heating. The relation of the gold to the potassium bromide, as well as the amounts of silver and silver bromide which are equivalent to the potassium bromide, were determined. The mean value thus adduced was 195.86. Kriiss worked with the same salt, and obtained the value 195.65; while Mallet, by analyses of gold chloride and bromide, and potassium auribromide, obtained the value 195.77.

Occlusion of Gas by Gold

T. Graham showed that gold is capable of occluding by volume 0.48% of hydrogen, 0.20% of nitrogen, 0.29% of carbon monoxide, and 0.16% of carbon dioxide. Varrentrapp pointed out that " cornets " from the assay of gold may retain gas if they are not strongly heated.

Occurrence and Distribution

Gold is found in nature chiefly in the metallic state, i.e. as " native gold," and less frequently in combination with tellurium, lead and silver. These are the only certain examples of natural combinations of the metal, the minute, though economically valuable, quantity often found in pyrites and other sulphides being probably only present in mechanical suspension. The native metal crystallizes in the cubic system, the octahedron being the commonest form, but other and complex combinations have been observed. Owing to the softness of the metal, large crystals are rarely well defined, the points being commonly rounded. In the irregular crystalline aggregates branching and moss-like forms are most common, and in Transylvania thin plates or sheets with diagonal structures are found. More characteristic, however, than the crystallized are the irregular forms,which, when large, are known as "nuggets" or " pepites," and when in pieces below - to z oz. weight as gold dust, the larger sizes being distinguished as coarse or nuggety gold, and the smaller as gold dust proper. Except in the larger nuggets, which may be more or less angular, or at times even masses of crystals, with or without associated quartz or other rock, gold is generally found bean-shaped or in some other flattened form, the smallest particles being scales of scarcely appreciable thickness, which, from their small bulk as compared with their surface, subside very slowly when suspended in water, and are therefore readily carried away by a rapid current. These form the " float gold " of the miner. The physical properties of native gold are generally similar to that of the melted metal.

Of the minerals containing gold the most important are sylvanite or graphic tellurium (Ag, Au) Tee, with 24 to 26%; calaverite, AuTe2, with 42%; nagyagite or foliate tellurium (Pb, Au)16 Sba(S, Te)24, with 5 to 9% of gold; petzite, (Ag, Au) 2 Te, and white tellurium. These are confined to a few localities, the oldest and best known being those of Nagyag and Offenbanya in Transylvania; they have also been found at Red Cloud, Colorado, in Calaveras county, California, and at Perth and Boulder, West Australia. The minerals of the second class, usually spoken of as " auriferous," are comparatively numerous. Prominent among these are galena and iron pyrites, the former being almost invariably gold-bearing. Iron pyrites, however, is of greater practical importance, being in some districts exceedingly rich, and, next to the native metal, is the most prolific source of gold. Magnetic pyrites, copper pyrites, zinc blende and arsenical pyrites are other and less important examples, the last constituting the gold ore formerly worked in Silesia. A native gold amalgam is found as a rarity in California, and bismuth from South America is sometimes rich in gold. Native arsenic and antimony are also very frequently found to contain gold and silver.

The association and distribution of gold may be considered under two different heads, namely, as it occurs in mineral veins - " reef gold," and in alluvial or other superficial deposits which are derived from the waste of the former - " alluvial gold." Four distinct types of reef gold deposits may be distinguished: (I) Gold may occur disseminated through metalliferous veins, generally with sulphides and more particularly with pyrites. These deposits seem to be the primary sources of native gold. (2) More common are the auriferous quartz-reefs - veins or masses of quartz containing gold in flakes visible to the naked eye, or so finely divided as to be invisible. (3) The " banket " formation, which characterizes the goldfields of South Africa, consists of a quartzite conglomerate throughout which gold is very finely disseminated. (4) The siliceous sinter at XII. 7 Mount Morgan, Queensland, which is obviously associated with hydrothermal action, is also gold-bearing. The genesis of the last three types of deposit is generally assigned to the simultaneous percolation of solutions of gold and silica, the auriferous solution being formed during the disintegration of the gold-bearing metalliferous veins. But there is much uncertainty as to the mechanism of the process; some authors hold that the soluble chloride is first formed, while others postulate the intervention of a soluble aurate.

In the alluvial deposits the associated minerals are chiefly those of great density and hardness, such as platinum, osmiridium and other metals of the platinum group, tinstone, chromic, magnetic and brown iron ores, diamond, ruby and sapphire, zircon, topaz, garnet, &c. which represent the more durable original constituents of the rocks whose distintegration has furnished the detritus.

Statistics of Gold Production

The supply of gold, and also its relation to the supply of silver, has, among civilized nations, always been of paramount importance in the economic questions concerning money (see Money and Bimetallism); in this article a summary of the modern gold-producing areas will be given, and for further details reference should be made to the articles on the localities named. The chief sources of the European supply during the middle ages were the mines of Saxony and Austria, while Spain also contributed. The supplies from Mexico and Brazil were important during the 16th and 17th centuries. Russia became prominent in 1823, and for fourteen years contributed the bulk of the supply. The United States (California) after 1848, and Australia after 1851, were responsible for enormous increases in the total production, which has been subsequently enhanced by discoveries in Canada, South Africa, India, China and other countries.

The average annual world's production for certain periods from 1801 to 1880 in ounces is given in Table I. The average TABLE I.


























6 ,35 0, 180



production of the five years 1881-1885 was the smallest since the Australian and Californian mines began to be worked in 1848-1849; the minimum 4,614,588 oz., occurred in 1882. It was not until after 1885 that the annual output of the world began to expand. Of the total production in 1876, 5,016,488 oz., almost the whole was derived from the United States, Australasia and Russia. Since then the proportion furnished by these countries has been greatly lowered by the supplies from South Africa, Canada, India and China. The increase of production has not been uniform, the greater part having occurred most notably since 1895. Among the regions not previously important as gold-producers which now contribute to the annual output, the most remarkable are the goldfields of South Africa (Transvaal and Rhodesia, the former of which were discovered in 1885). India likewise has been added to the list, its active production having begun at about the same time as that of South Africa. The average annual product of India for the period 1886 to 1899 inclusive was £698,208, and its present annual product averages about 550,000 oz., or about £2,200,000, obtained almost wholly from the free-milling quartz veins of the Colar goldfields in Mysore, southern India. In 1900 the output was valued at £1,891,804, in 1905 at £2,450,536, and in 1908 at £2,270,000. Canada, too, assumed an important rank, having contributed in 1900 £5,583,300; but the output has since steadily declined to £1,973,000 in 1908. The great increase during the few years preceding 1899 was due to the development of the goldfields of the North-Western Territory, especially British Columbia. From the district of Yukon (Klondike, &c.) £2,800,000 was obtained in 1899, wholly from alluvial workings, but the progress made since has been slower than was expected by sanguine people. It is, however, probable that the North-Western Territory will continue to yield gold in important quantities for some time to come.

The output of the United States increased from £7,050,000 in 1881 to £16,085,567 in 1900, £17,916,000 in 1905, and to £20,065,000 in 1908. This increase was chiefly due to the exploitation of new goldfields. The fall in the price of silver stimulated the discovery and development of gold deposits, and many states formerly regarded as characteristically silver districts have become important as gold producers. Colorado is a case in point, its output having increased from about £600,000 in 1880 to £6,065,000 in 1900; it was £5,139,800 in 1905. Somewhat more than one-half of the Colorado gold is obtained from the Cripple Creek district. Other states also showed a largely augmented product. On the other hand, the output of California, which was producing over £3,000,000 per annum in 1876, has fallen off, the average annual output from 1876 to 1900 being £2,800,000; in 1905 the yield was £3,839,000. This decrease was largely caused by the practical suspension for many years of the hydraulic mining operations, in preparation for which millions of dollars had been expended in deep tunnels, flumes, &c., and the active continuance of which might have been expected to yield some £2,000,000 of gold annually. This interruption, due to the practical prohibition of the industry by the United States courts, on the ground that it was injuring, through the deposit of tailings, agricultural lands and navigable streams, was lessened, though not entirely removed, by compromises and regulations which permit, under certain restrictions, the renewed exploitation of the ancient river-beds by the hydraulic method. On the other hand, the progressive reduction of mining and metallurgical costs effected by improved transportation and machinery, and the use of high explosives, compressed air, electric-power transmission, &c., resulted in California (as elsewhere) in a notable revival of deep mining. This was especially the case on the " Mother Lode,".where highly promising results were obtained. Not only is vein-material formerly regarded as unremunerative now extracted at a profit, but in many instances increased gold-values have been encountered below zones of relative barrenness, and operators have been encouraged to make costly preparations for really deep mining - more than 3000 ft. below the surface. The gold product of California, therefore, may be fairly expected to maintain itself, and, indeed, to show an advance. Alaska appeared in the list of gold-producing countries in 1886, and gradually increased its annual output until 1897, when the country attracted much attention with a production valued at over £500,000; the opening up of new workings has increased this figure immensely, from about £1,400,000 in 1901 to £3,006,500 in 1905. The Alaska gold was derived almost wholly from the large low-grade quartz mines of Douglas Island prior to 1899, but in that year an important district was discovered at Cape Nome, on the north-western coast. The result of a few months' working during that year was more than £500,000 of gold, and a very much larger annual output may reasonably be anticipated in the future; in 1905 it was about £900,000. The gold occurs in alluvial deposits designated as gulch-, bar-, beach-, tundraand bench-placers. The tundra is a coastal plain, swampy and covered with undergrowth and underlaid by gravel. The most interesting and, thus far, the most productive are the beach deposits, similar to those on the coast of Northern California. These occur in a strip of comparatively fine gravel and sand, 150 yds. wide, extending along the shore. The gold is found in stratified layers, with " ruby " and black sand. The " ruby " sand consists chiefly of fine garnets and magnetites, with a few rose-quartz grains. Further exploration of the interior will probably result in the discovery of additional gold districts.

Mexico, from a gold production of £200,000 in 1891, advanced to about £1,881,800 in 1900 and to about £3,221,000 in 1905. Of this increase, a considerable part was derived from gold-quartz mining, though much was also obtained as a by-product in the working of the ores of other metals. The product of Colombia, Venezuela, the Guianas, Brazil, Uruguay, Argentina, Chile, Bolivia, Peru and Ecuador amounted in 1900 to £2,481,000 and to £2,046,000 in 1905.

In 1876 Australasia produced £7,364,000, of which Victoria contributed £3,984,000. The annual output of Victoria declined until the year 1892, when it began to increase rapidly, but not to its former level, the values for 1900 and 1905 being £3,142,000 and £3,138,000. There has been an important increase in Queensland, which advanced from £1,696,000 in 1876 to £2,843,000 in 1900, and subsequently declined to £2,489,000 in 1905. There has been no increase, and, indeed, no large fluctuation until quite recently in the output of New Zealand, which averaged £1,054,000 per annum from 1876 to 1898, but the production of the two years 190oand 1905 rose to £1,425,459 and £2,070,407 respectively. By far the most important addition to the Australasian product has come fromWestAustralia,which began its production in 1887 - about the time of the inception of mining at Witwatersrand ("the Rand") in South Africa-and by continuous increase, which assumed large proportions towards the close of the 19th century, was £6,426,000 in 1899, £6,179,000 in 1900, and L8,212,000 in 1905. The total Australasian production in 1908 was valued at £14,708,000.

Undoubtedly the greatest of the gold discoveries made in the latter half of the 19th century was that of the Witwatersrand district in the Transvaal. By reason of its unusual geological character and great economic importance this district deserves a more extended description. The gold occurs in conglomerate beds, locally known as "banket." There are several series of parallel beds, interstratified with quartzite and schist, the most important being the "main reef" series. The gold in this conglomerate reef is partly of detrital origin and partly of the genetic character of ordinary vein-gold. The formation is noted for its regularity as regards both the thickness and the gold-tenor of the ore-bearing reefs, in which respect it is unparalleled in the geology of the auriferous formations. The gold carries, on an average, £2 per ton, and is worked by ordinary methods of goldmining, stamp-milling and cyaniding. In 18 99, 57 62 stamps were in operation, crushing 7,331,446 tons of ore, and yielding £15,134,000, equivalent to 25.5% of the world's production. Of this, 80% came from within 12 m. of Johannesburg. After September 1899 operations were suspended, almost entirely owing to the Boer War, but on the 2nd of May 1901 they were started again. In 1905 the yield was valued at £20,802,074, and in 1909 at £30,925,788. So certain is the ore-bearing formation that engineers in estimating its auriferous contents feel justified in assuming, as a factor in their calculations, a vertical extension limited only by the lowest depths at which mining is feasible. On such a basis they arrived at more than £600,000,000 as the available gold contained in the Witwatersrand conglomerates. This was a conservative estimate, and was made before the full extent of the reefs was known; in 1904 Lionel Phillips stated that the main reef series had been proved for 61 m., and he estimated the gold remaining to be mined to be worth £2,500,000,000. Deposits similar to the Witwatersrand banket occur in Zululand, and also on the Gold Coast of Africa. In Rhodesia, the country lying north of the Transvaal, where gold occurs in well-defined quartzveins, there is unquestionable evidence of extensive ancient workings. The economic importance of the region generally has been fully proved. Rhodesia produced £386,148 in 1900 and £722,656 in 1901, in spite of the South African War; the product for 1905 was valued at £1,480,449, and for 1908 at L2,526,000.

The gold production of Russia has been remarkably constant, averaging £4,899,262 per annum; the gold is derived chiefly from placer workings in Siberia.

The gold production of China was estimated for 1899 at £1,328,238 and for 1900 at £860,00o; it increased in 1901 to about £1,700,000, to fall to £340,000 in 1905; in 1906 and 1907 it recovered to about £1,000,000.

Production of Certain Countries, 1881-Ig08 (in oz.). Alloys.-Gold forms alloys with most metals, and of these many are of great importance in the arts. The alloy with mercury-gold amalgam-is so readily formed that mercury is one of the most powerful agents for extracting the precious metal. With 10% of gold present the amalgam is fluid, and with 12.5% pasty, while with 13% it consists of yellowish-white crystals. Gold readily alloys with silver and copper to form substances in use from remote times for money, jewelry and plate. Other metals which find application in the metallurgy of gold by virtue of their property of extracting the gold as an alloy are lead, which combines very readily when molten, and which can afterwards be separated by cupellation, and copper, which is separated from the gold by solution in acids or by electrolysis; molten lead also extracts gold from the copper-gold alloys. The relative amount of gold in an alloy is expressed in two ways: (1) as " fineness," i.e. the amount of gold in 1000 parts of alloy; (2) as " carats," i.e. the amount of gold in 24 parts of alloy. Thus, pure gold is woo " fine " or 24 carat. In England the following standards are used for plate and jewelry: 375, 500, 62 5, 75 0 and 916.6, corresponding to 9, 12, 15, 18 and 22 carats, the alloying metals being silver and copper in varying proportions. In France three alloys of the following standards are used for jewelry, 920, 840 and 750. A greenish alloy used by goldsmiths contains 70% of silver and 30% of gold. " Blue gold " is stated to contain 75% of gold and 25% of iron. The Japanese use for ornament an alloy of gold and silver, the standard of which varies from 350 to 500, the colour of the precious metal being developed by " pickling " in a mixture of plum-juice, vinegar and copper sulphate. They may be said to possess a series of bronzes, in which gold and silver replace tin and zinc, all these alloys being characterized by patina having a wonderful range of tint. The common alloy, Shi-ya-ku-Do, contains 70% of copper and 30% of gold; when exposed to air it becomes coated with a fine black patina, and is much used in Japan for sword ornaments. Gold wire may be drawn of any quality, but it is usual to add 5 to 9 dwts. of copper to the pound. The " solders " used for red gold contain 1 part of copper and 5 of gold; for light gold, 1 part of copper, I of silver and 4 of gold.

Gold and Silver.-Electrum is a natural alloy of gold and silver. Matthiessen observed that the density of alloys, the composition of which varies from AuAg 6 to Au 6 Ag, is greater than that calculated from the densities of the constituent metals. These alloys are harder, more fusible and more sonorous than pure gold. The alloys of the formulae AuAg, AuAg 2, AuAg 4 and AuAg 2 o are perfectly homogeneous, and have been studied by Levol. Molten alloys containing more than 80% of silver deposit on cooling the alloy AuAgs, little gold remaining in the mother liquor.












1,475, 161

















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60 9,7 81

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4, 1 59, 220

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779, 181


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7, 2 7 0 ,4 6 4

399, 8 44

495,9 6 5



4,374, 82 7



3,557,7 0 5

7,9 8 3,34 8

4 62 ,4 6 7

5 0 4,3 0 9

1, 182 ,445

1 ,497, 0 7 6



Gold and Zinc.-When present in small quantities zinc renders gold TABLE II.-Gold brittle, but it may be added to gold in larger quantities without destroying the ductility of the precious metal; Peligot proved that a triple alloy of gold, copper and zinc, which contains 5.8% of the lastnamed, is perfectly ductile. The alloy of II parts gold and i part of zinc is, however, stated to be brittle.

Gold and Tin. - Alchorne showed that gold alloyed with th part of tin is sufficiently ductile to be rolled and stamped into coin, provided the metal is not annealed at a high temperature. The alloys of tin and gold are hard and brittle, and the combination of the metals is attended with contraction; thus the alloy SnAu has a density 14.243, instead of 14.828 indicated by calculation. Matthiessen and Bose obtained large crystals of the alloy Au 2 Sn 5, having the colour of tin, which changed to a bronze tint by oxidation.

Gold and Iron. - Hatchett found that the alloy of i i parts gold and i part of iron is easily rolled without annealing. In these proportions the density of the alloy is less than the mean of its constituent metals.

Gold and Palladium

These metals are stated to alloy in all proportions. According to Chenevix, the alloy composed of equal parts of the two metals is grey, is less ductile than its constituent metals and has the specific gravity i i. 08. The alloy of 4 parts of gold and i part of palladium is white, hard and ductile. Graham showed that a wire of palladium alloyed with from 24 to 25 parts of gold does not exhibit the remarkable retraction which, in pure palladium, attends its loss of occluded hydrogen.

Gold and Platinum. - Clarke states that the alloy of equal parts of the two metals is ductile, and has almost the colour of gold. Gold and Rhodium. - Gold alloyed with 4th or 1th of rhodium is, according to Wollaston,very ductile,infusible and of the colour of gold. Gold and Iridium. - Small quantities of iridium do not destroy the ductility of gold, but this is probably because the metal is only disseminated through the mass, and not alloyed, as it falls to the bottom of the crucible in which the gold is fused.

Gold and Nickel

Eleven parts of gold and i of nickel yield an alloy resembling brass.

Gold and Cobalt

Eleven parts of gold and i of cobalt form a brittle alloy of a dull yellow colour.


Aurous oxide, Au 2 0, is obtained by cautiously adding potash to a solution of aurous bromide, or by boiling mixed solutions of auric chloride and mercurous nitrate. It forms a dark-violet precipitate which dries to a greyish-violet powder. When freshly prepared it dissolves in cold water to form an indigocoloured solution with a brownish fluorescence of colloidal aurous oxide; it is insoluble in hot water. This oxide is slightly basic. Auric oxide, Au203, is a brown powder, decomposed into its elements when heated to about 250° or on exposure to light. When a concentrated solution of auric chloride is treated with caustic potash, a brown precipitate of auric hydrate, Au(OH) 3, is obtained, which, on heating, loses water to form auryl hydrate, AuO(OH), and auric oxide, Au 2 0 3. It functions chiefly as an acidic oxide, 'being less basic than aluminium oxide, and forming no stable oxy-salts. It dissolves in alkalis to form well-defined crystalline salts; potassium aurate, KAu0 2.3H 2 O, is very soluble in water, and is used in electrogilding. With concentrated ammonia auric oxide forms a black, highly explosive compound of the composition AuN2H3.3H20, named " fulminating gold "; this substance is generally considered to be Au(NH 2)NH. 3H20, but it may be an ammine of the formula [Au(NH 3) 2 (OH) 2 ]OH. Other oxides, e.g. Au 2 0 2, have been described.

Aurous chloride, AuCl, is obtained as a lemon-yellow, amorphous powder, insoluble in water, by heating auric chloride to 185°. It begins to decompose into gold and chlorine at 185°, the decomposition being complete at 230°; water decomposes it into gold and auric chloride. Auric chloride, or gold trichloride, AuC1 3, is a dark rubyred or reddish-brown, crystalline, deliquescent powder obtained by dissolving the metal in aqua regia. It is also obtained by carefully evaporating a solution of the metal in chlorine water. The gold chloride of commerce, which is used in photography, is really a hydrochloride, chlorauric or aurichloric acid, HAuC1 4.3H 2 O, and is obtained in long yellow needles by crystallizing the acid solution. Corresponding to this acid, a series of salts, named chloraurates or aurichlorides, are known. The potassium salt is obtained by crystallizing equivalent quantities of potassium and auric chlorides. Light-yellow monoclinic needles of 2KAuC1 4

H 2 O are deposited from warm, strongly acid solutions, and transparent rhombic tables of KAuCl 4.2H 2 O from neutral solutions. By crystallizing an aqueous solution, red crystals of AuC1 3.2H 2 O are obtained. Auric chloride combines with the hydrochlorides of many organic bases - amines, alkaloids, &c. - to form characteristic compounds. Gold dichloride, probably Au 2 C1 4, =Au.AuC1 4, aurous chloraurate, is said to be obtained as a dark-red mass by heating finely divided gold to 140°- 170° in chlorine. Water decomposes it into gold and auric chloride. The bromides and iodides resemble the chlorides. Aurous bromide, AuBr, is a yellowish-green powder obtained by heating the tribromide to 140°; auric bromide, AuBr 3, forms reddish-black or scarlet-red leafy crystals, which dissolve in water to form a reddishbrown solution,and combines with bromides to form bromaurates corresponding to the chloraurates. Aurous iodide, Aul, is a light-yellow, sparingly soluble powder obtained, together with free iodine, by adding potassium iodide to auric chloride; auric iodide, Au13, is formed as a dark-green powder at the same time, but it readily decomposes to aurous iodide and iodine. Aurous iodide is also obtained as a green solid by acting upon gold with iodine. The iodaurates, correspond to the chlorand bromaurates; the potassium salt, KAuI 4, forms highly lustrous, intensely black, four-sided prisms.

Aurous cyanide, AuCN, forms yellow, microscopic, hexagonal tables, insoluble in water, and is obtained by the addition of hydrochloric acid to a solution of potassium aurocyanide, KAu(CN)2. This salt is prepared by precipitating a solution of gold in aqua regia by ammonia, and then introducing the well-washed precipitate into a boiling solution of potassium cyanide. The solution is filtered and allowed to cool, when colourless rhombic pyramids of the aurocyanide separate. It is also obtained in the action of potassium cyanide on gold in the presence of air, a reaction utilized in the MacArthur-Forrest process of gold extraction (see below). Auric cyanide, Au(CN) 3, is not certainly known; its double salts, however, have been frequently described. Potassium auricyanide, 2KAu(CN) 4.3H 2 O, is obtained as large, colourless, efflorescent tablets by crystallizing concentrated solutions of auric chloride and potassium cyanide. The acid, auricyanic acid, 2HAu (CN) 4.3H20, is obtained by treating the silver salt (obtained by precipitating the potassium salt with silver nitrate) with hydrochloric acid; it forms tabular crystals, readily soluble in water, alcohol and ether.

Gold forms three sulphides corresponding to the oxides; they readily decompose on heating. Aurous sulphide, Au 2 S, is a brownishblack powder formed by passing sulphuretted hydrogen into a solution of potassium aurocyanide and then acidifying. Sodium aurosulphide, NaAuS

4H 2 O, is prepared by fusing gold with sodium sulphide and sulphur, the melt being extracted with water, filtered in an atmosphere of nitrogen, and evaporated in a vacuum over sulphuric acid. It forms colourless, monoclinic prisms, which turn brown on exposure to air. This method of bringing gold into solution is mentioned by Stahl in his Observationes ChymicoPhysico-Medicae; he there remarks that Moses probably destroyed the golden calf by burning it with sulphur and alkali (Ex. xxxii. 20). Auric sulphide, Au 2 S 31 is an amorphous powder formed when lithium aurichloride is treated with dry sulphuretted hydrogen at - 10°. It is very unstable, decomposing into gold and sulphur at 200°.

Oxy-salts of gold are almost unknown, but the sulphite and thiosulphate form double salts. Thus by adding acid sodium sulphite to, or by passing sulphur dioxide at 50° into, a solution of sodium aurate, the salt, 3Na 2 SO 3

Au 2 SO 3.3H20 is obtained, which, when precipitated from its aqueous solution by alcohol, forms a purple powder, appearing yellow or green by reflected light. Sodium aurothiosulphate, 3Na 2 S 2 O 3

Au2S203.4H20, forms colourless needles; it is obtained in the direct action of sodium thiosulphateongoldinthe presence of an oxidizing agent, or by the addition of a dilute solution of auric chloride to a sodium thiosulphate solution.

Mining and Metallurgy. The various deposits of gold may be divided into two classes- " veins " and " placers." The vein mining of gold does not greatly differ from that of similar deposits of metals (see Mineral Deposits). In the placer or alluvial deposits, the precious metal is found usually in a water-worn condition imbedded in earthy matter, and the method of working all such deposits is based on the disintegration of the earthy matter by the action of a stream of water, which washes away the lighter portions and leaves the denser gold. In alluvial deposits the richest ground is usually found in contact with the "bed rock"; and, when the overlying cover of gravel is very thick, or, as sometimes happens, when the older gravel is covered with a flow of basalt, regular mining by shafts and levels, as in what are known as tunnel-claims, may be required to reach the auriferous ground.

The extraction of gold may be effected by several methods; we may distinguish the following leading types: 1. By simple washing, i.e. dressing auriferous sands,gravels,&c.; 2. By amalgamation, i.e. forming a gold amalgam, afterwards removing the mercury by distillation; 3. By chlorination, i.e. forming the soluble gold chloride and then precipitating the metal; 4. By the cyanide process, i.e. dissolving the gold in potassium cyanide solution, and then precipitating the metal; 5. Electrolytically, generally applied to the solutions obtained in processes (3) and (4).

1. Extraction of Gold by Washing. - In the early days of goldwashing in California and Australia, when rich alluvial deposits were common at the surface, the most simple appliances sufficed. The most characteristic is the " pan," a circular dish of sheetiron or " tin," with sloping sides about 13 or 14 in. in diameter. The pan, about two-thirds filled with the " pay dirt " to be washed, is held in the stream or in a hole filled with water. The larger stones having been removed by hand, gyratory motion is given to the pan by a combination of shaking and twisting movements so as to keep its contents suspended in the stream of water, which carries away the bulk of the lighter material, leaving the heavy minerals, together with any gold which may have been present. The washing is repeated until enough of the enriched sand is collected, when the gold is finally recovered by careful washing or " panning out " in a smaller pan. In Mexico and South America, instead of the pan, a wooden dish or trough, known as " batea," is used.

The " cradle " is a simple appliance for treating somewhat larger quantities, and consists essentially of a box, mounted on rockers, and provided with a perforated bottom of sheet iron in which the " pay dirt " is placed. Water is poured on the dirt, and the rocking motion imparted to the cradle causes the finer particles to pass through the perforated bottom on to a canvas screen, and thence to the base of the cradle, where the auriferous particles accumulate on transverse bars of wood, called " riffles." The " tom " is a sort of cradle with an extended sluice placed on an incline of about I in 12. The upper end contains a perforated riddle plate which is placed directly over the riffle box, and under certain circumstances mercury may be placed behind the riffles. Copper plates amalgamated with mercury are also used when the gold is very fine, and in some instances amalgamated silver coins have been used for the same purpose. Sometimes the stuff is disintegrated with water in a " puddling machine," which was used, especially in Australia, when the earthy matters are tenacious and water scarce. The machine frequently resembles a brickmaker's wash-mill, and is worked by horse or steam power.

In workings on a larger scale, where the supply of water is abundant, as in California, sluices were generally employed. They are shallow troughs about 12 ft. long, about 16 to 20 in. wide and I ft. in depth. The troughs taper slightly so that they can be joined in series, the total length often reaching several hundred feet. The incline of the sluice varies with the conformation of the ground and the tenacity of the stuff to be washed, from 1 in 16 to I in 8. A rectangular trough of boards, whose dimensions depend chiefly on the size of the planks available, is set up on the higher part of the ground at one side of the claim to be worked, upon trestles or piers of rough stone-work, at such an inclination that the stream may carry off all but the largest stones, which are kept back by a grating of boards about 2 in. apart. The gravel is dug by hand and thrown in at the upper end, the stones kept back being removed at intervals by two men with four-pronged steel forks. The floor of the sluice is laid with riffles made of strips of wood 2 in. square laid parallel to the direction of the current, and at other points with boards having transverse notches filled with mercury. These were known originally as Hungarian riffles.

In larger plant the upper ends of the sluices are often cut in rock or lined with stone blocks, the grating stopping the larger stones being known as a " grizzly." In order to save very fine and especially rusty particles of gold, so-called " under-current sluices " are used; these are shallow wooden tanks, 50 sq. yds. and upwards in area, which are placed somewhat below the main sluice, and communicate with it above and below, the entry being protected by a grating so that only the finer material is admitted. These are paved with stone blocks or lined with mercury riffles, so that from the greatly reduced velocity of flow, due to the sudden increase of surface, the finer particles of gold may collect. In order to save finely divided gold, amalgamated copper plates are sometimes placed in a nearly level position, at a considerable distance from the head of the sluice, the gold which is retained in it being removed from time to time. Sluices are often made double, and they are usually cleaned up - that is, the deposit rich in gold is removed from them - once a week.

The " pan " is now only used by prospectors, while the " cradle " and " tom " are practically confined to the Chinese; the sluice is considered to be the best contrivance for washing gold gravels.

2. The Amalgamation Process. - This method is employed to extract gold from both alluvial and reef deposits: in the first case it is combined with " hydraulic mining," i.e. disintegrating auriferous gravels by powerful jets of water, and the sluice system described above; in the second case the vein stuff is prepared by crushing and the amalgamation is carried out in mills.

Hydraulic mining has for the most part been confined to the country of its invention, California, and the western territories of America, where the conditions favourable for its use are more fully developed than elsewhere - notably the presence of thick banks of gravel that cannot be utilized by other methods, and abundance of water, even though considerable work may be required at times to make it available. The general conditions to be observed in such workings may be briefly stated as follows: (I) The whole of the auriferous gravel, down to the " bed rock," must be removed, - that is, no selection of rich or poor parts is possible; (2) this must be accomplished by the aid of water alone, or at times by water supplemented by blasting; (3) the conglomerate must be mechanically disintegrated without interrupting the whole system; (4) the gold must be saved without interrupting the continuous flow of water; and (5) arrangements must be made for disposing of the vast masses of impoverished gravel.

The water is brought from a ditch on the high ground, and through a line of pipes to the distributing box, whence the branch pipes supplying the jets diverge. The stream issues through a nozzle, termed a " monitor " or " giant," which is fitted with a ball and socket joint, so that the direction of the jet may be varied through considerable angles by simply moving a handle. The material of the bank being loosened by blasting and the cutting action of the water, crumbles into holes, and the superincumbent mass, often with large trees and stones, falls into the lower ground. The stream, laden with stones and gravel, passes into the sluices, where the gold is recovered in the manner already described. Under the most advantageous conditions the loss of gold may be estimated at 15 or 20%, the amount recovered representing a value of about two shillings per ton of gravel treated. The loss of mercury is about the same, from 5 to 6 cwt. being in constant use per mile of sluice.

In working auriferous river-beds, dredges have been used with considerable success in certain parts of New Zealand and on the Pacific slope in America. The dredges used in California are almost exclusively of the endless-chain bucket or steam-shovel pattern. Some dredges have a capacity under favourable conditions of over 2000 cub. yds. of gravel daily. The gravel is excavated as in the ordinary form of endless-chain bucket dredge and dumped on to the deck of the dredge. It then passes through screens and grizzlies to retain the coarse gravel, the finer material passing on to sluice boxes provided with riffles, supplied with mercury. There are belt conveyers for discharging the gravel and tailings at the end of the vessel remote from the buckets. The water necessary to the process is pumped from the river; as much as 2000 gallons per minute is used on the larger dredges.

The dressing or mechanical preparation of vein stuff containing gold is generally similar to that of other ores (see ORE-Dressing), except that the precious metal should be removed from the waste substances as quickly as possible, even although other minerals of value that are subsequently recovered may be present. In all cases the quartz or other vein stuff must be reduced to a very fine powder as a preliminary to further operations. This may be done in several ways, e.g. either (I) by the Mexican crusher or arrastra, in which the grinding is effected upon a bed of stone, over which heavy blocks of stone attached to cross arms are dragged by the rotation of the arms about a central spindle, or (2) by the Chilean mill or trapiche, also known as the edge-runner, where the grinding stones roll upon the floor, at the same time turning about a central upright - contrivances which are mainly used for the preparation of silver ores; but by far the largest proportion of the gold quartz of California, Australia and Africa is reduced by (3) the stamp mill, which is similar in principle to that used in Europe for the preparation of tin and other ores.

The stamp mill was first used in California, and its use has since spread over the whole world. In the mills of the Californian type the stamp is a cylindrical iron pestle faced with a chilled cast iron shoe, removable so that it can be renewed when necessary, attached to a round iron rod or lifter, the whole weighing from 600 to 900 lb; stamps weighing 1320 lb are in use in the Transvaal. The lift is effected by cams acting on the under surface of tappets, and formed by cylindrical boxes keyed on to the stems of the lifter about onefourth of their length from the top. As, however, the cams, unlike those of European stamp mills, are placed to one side of the stamp, the latter is not only lifted but turned partly round on its own axis, whereby the shoes are worn down uniformly. The height of lift may be between 4 and 18 in., and the number of blows from 30 to over loo per minute. The stamps are usually arranged in batteries of five; the order of working is usually I, 4, 2, 5, 3, but other arrangements, e.g. I, 3, 5, 2, 4, and 1, 5, 2, 4, 3, are common. The stuff, previously broken to about 2-in. lumps in a rock-breaker, is fed in through an aperture at the back of the " battery box," a constant supply of water is admitted from above, and mercury in a finely divided state is added at frequent intervals. The discharge of the comminuted material takes place through an aperture, which is covered by a thin steel plate perforated with numerous slits about Ath in. broad and z in. long, a certain volume being discharged at every blow and carried forward by the flushing water over an apron or table in front, covered by copper plates filled with mercury. Similar plates are often used to catch any particles of gold that may be thrown back, while the main operation is so conducted that the bulk of the gold may be reduced to the state of amalgam by bringing the two metals into intimate contact under the stamp head, and remain in the battery. The tables in front are laid at an incline of about 8° and are about 13 ft. long; they collect from 10 to 15% of the whole gold; a further quantity is recovered by leading the sands through a gutter about 16 in. broad and 120 ft. long, also lined with amalgamated copper plates, after the pyritic and other heavy minerals have been separated by depositing in catch pits and other similar contrivances.

When the ore does not contain any considerable amount of free gold mercury is not, as a rule, used during the crushing, but the amalgamation is carried out in a separate plant. Contrivances of the most diverse constructions have been employed. The most primitive is the rubbing together of the concentrated crushings with mercury in iron mortars. Barrel amalgamation, i.e. mixing the crushings with mercury in rotating barrels, is rarely used, the process being wasteful, since the mercury is specially apt to be " floured " ( see below).

At Schemnitz, Kerpenyes, Kreuzberg and other localities in Hungary, quartz vein stuff containing a little gold, partly free and partly associated with pyrites and galena, is, after stamping in mills, similar to those described above, but without rotating stamps, passed through the so-called " Hungarian gold mill " or " quick-mill." This consists of a cast-iron pan having a shallow cylindrical bottom holding mercury, in which a wooden muller, nearly of the same shape as the inside of the pan, and armed below with several projecting blades, is made to revolve by gearing wheels. The stuff from the stamps is conveyed to the middle of the muller, and is distributed over the mercury, when the gold subsides, while the quartz and lighter materials are guided by the blades to the circumference and are discharged, usually into a second similar mill, and subsequently pass over blanket tables, i.e. boards covered with canvas or sacking, the gold and heavier particles becoming entangled in the fibres. The action of this mill is really more nearly analogous to that of a centrifugal pump, as no grinding action takes place in it. The amalgam is cleaned out periodically - fortnightly or monthly - and after filtering through linen bags to remove the excess of mercury, it is transferred to retorts for distillation (see below).

Many other forms of pan-amalgamators have been devised. The Laszlo is an improved Hungarian mill, while the Piccard is of the same type. In the Knox and Boss mills, which are also employed for the amalgamation of silver ores, the grinding is effected between flat horizontal surfaces instead of conical or curved surfaces as in the previously described forms.

One of the greatest difficulties in the treatment of gold by amalgamation, and more particularly in the treatment of pyrites, arises from the so-called " sickening " or " flouring " of the mercury; that is, the particles, losing their bright metallic surfaces, are no longer capable of coalescing with or taking up other metals. Of the numerous remedies proposed the most efficacious is perhaps sodium amalgam. It appears that amalgamation is often impeded by the tarnish found on the surface of the gold when it is associated with sulphur, arsenic, bismuth, antimony or tellurium. Henry Wurtz in America (1864) and Sir William Crookes in England (1865) made independently the discovery that, by the addition of a small quantity of sodium to the mercury, the operation is much facilitated. It is also stated that sodium prevents both the " sickening " and the " flouring " of the mercury which is produced by certain associated minerals. The addition of potassium cyanide has been suggested to assist the amalgamation and to prevent " flouring," but Skey has shown that its use is attended with loss of gold.

Separation of Gold from the Amalgam

The amalgam is first pressed in wetted canvas or buckskin in order to remove excess of mercury. Lumps of the solid amalgam, about 2 in. in diameter, are introduced into an iron vessel provided with an iron tube that leads into a condenser containing water. The distillation is then effected by heating to dull redness. The amalgam yields about 30 to 40% of g

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Bibliography Information
Chisholm, Hugh, General Editor. Entry for 'Gold'. 1911 Encyclopedia Britanica. 1910.

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